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79%, which is much higher than that of MH-12 alone (8.18%). Conclusively, the study furnishes a deeper understanding of the intricacies involved in the structural modification of sensitizers/co-sensitizers in achieving an enhanced performance of the devices.Unique hierarchical olive-like yolk-shell structured MnO@C composites were customized via an ingenious and effective biomass strategy. This structure, with internal void spaces, accommodated the volume variations of MnO, and the N-doped porous carbon shells ensured the rapid transpor