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Tuning of pore function and size (surface area) are two key factors that play important roles in the performance of metal-organic-frameworks (MOFs) as catalysts. The catalytic performance of two bulk and nanosized MOFs with different functional groups such as a Brønsted base and Lewis acid was studied in line with the sustainable development of catalysts and green chemistry principles. Bifunctional imine decorated TMU-33, ([Cd3(BDC)3(OPP)(DMF)2]·2DMA)n (TMU-33), (OPP N,N'-(oxybis(4,1-phenylene))bis(1-(pyridin-4yl)methanimine)), with an

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