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Ag nanoparticles exhibit various colors depending on their localized surface plasmon resonance (LSPR). Based on this phenomenon, Ag deposition-based electrochromic devices can represent various optical states in a single device such as the three primary colors (cyan, magenta, and yellow), silver mirror, black and transparent. A control of the morphology of Ag nanoparticles can lead to dramatic changes in color, as their size and shape influence the LSPR band. In this research, we focused on the diffusion rate of Ag+ ions when Ag nanopartic