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Thermal manipulation in nanowires (NWs) is of great significance for NW-based applications in the area of heat management and energy harvesting. Here, we experimentally demonstrate thermal conductivity manipulation and thermal rectification in π-stacked metallophthalocyanine (MPcs) NWs. By electron beam (E-beam) irradiation with a controllable dose, the thermal conductance of MPcs NWs can be continuously tuned to the desired values. Three thermal rectifiers were further tested on crystal-amorphous heterostructures and the thermal rectif
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