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Hydrate-based desalination (HBD), a type of freezing-based desalination, can concentrate salts of saline water and produce fresh water via hydrate crystal formation. In this study, the thermodynamic stability, crystallographic information, and kinetic growth behavior of HFC-152a hydrate were investigated to estimate the desalination efficiency of HBD. The phase equilibria revealed that the HFC-152a hydrate could be formed at a higher temperature in the presence of NaCl (0 wt%, 3.5 wt%, and 8.0 wt%) than the HFC-134a hydrate at 0.3 MPa.