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Such a solvent- and acid-assisted topology evolution represents a general approach that can be used with other tetratopic carboxylate linkers to realize structural diversity. The present work demonstrates an effective structure designing strategy by controlling synthetic conditions, which may prove to be powerful for customized synthesis of MOFs with specific structure and functionality.The interaction of the atomic coinage metal cations Cu+, Ag+, and Au+ with O2, a weak ligand, and C6H6, a strong ligand, was investigated with measureme
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