https://www.selleckchem.com/pr....oducts/CHR-2797(Tose
The syntheses of the homoleptic bis(arene) niobium cations [Nb(arene)2 ]+ (arene = C6 H3 Me3 , C6 H5 Me) with 16 valence electrons and heteroleptic arene-carbonyl cations [(CO)Nb(arene)2 ]+ (arene = C6 H3 Me3 , C6 H5 Me) and [(arene)M(CO)4 ]+ (arene = C6 H3 Me3 , C6 H6 ) obeying 18 valence electrons are described. Stabilization of these complexes was achieved by using the weakly coordinating anions [Al(ORF )4 ]- or [FAl(ORF )3 2 ]- (RF = C(CF3 )3 ). The limits of two synthesis routes starting from neutral Nb(arene)2 (arene