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We additionally quantified the oversaturation of fuel necessary for nucleation of a nanobubble and demonstrated its reliance upon the outer lining morphology.A visible-light-induced, catalyst-free radical cross-coupling cyclization of diselenides or disulfides with N-allylbromodifluoroacetamide was created. This developed protocol displays good functional team threshold and affords an assortment of 4-thio- and 4-seleno-substituted 3,3-difluoro-γ-lactams in modest to great yields

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