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Artificial utility of this technique is evident through the planning of biologically potent spirocyclic oxindoles and tetrahydrofuranoindolines.Low-temperature anaerobic methane transformation to methanol (MTM) utilizing copper ion-exchanged mordenite (Cu-MOR) because the catalyst and liquid while the sole source of oxygen is guaranteeing for sustainable utilization of methane. Integrating in situ calorimetric, spectroscopic, and architectural methodologies, we report a s