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The electrochemical energy storage of lithium and sodium ions from aqueous solutions in binary metal oxides is of great interest for renewable energy storage applications. Binary metal oxides are of interest for aqueous energy storage due to their better structural stability and electronic conductivity and tunability of redox potentials. They have also been widely studied as novel electrodes for supercapacitors. The interactions between water and lithium/sodium ions, and water and binary metal oxide surface determine the electrochemical
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