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This work explores the effects of three selected fluoroalcohols - 1,1,1,3,3,3-hexafluoroisopropanol (HFIP), 1,1,1,3,3,3-hexafluorotert‑butyl alcohol (HFT and hexafluoro-2,3-(trifluoromethyl)-2,3-butanediol (PP) as novel eluent additives and their effect on the retention of basic and acidic analytes, using a reversed phase (RP) column with a fluorophenyl (PFP) stationary phase. In order to observe the changes in the model analytes' retention, chromatograms were obtained at multiple (5.0; 6.0; 7.0; 8.5; 9.0 and 9.5) pH values depending o