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Salts with asymmetric (fluorosulfonyl)(trifluoromethanesulfonyl)imide (FTFSI) anions have recently been shown to suppress crystallization of water-in-salt electrolytes, enabling low-temperature operation of high-voltage aqueous rechargeable batteries. To clarify the underlying mechanism for the kinetic suppression of crystallization, we investigate the local solution structures and dynamic behaviors of water-in-salt electrolytes based on the asymmetric FTFSI anion and its symmetric anion analogues by Raman spectroscopy and molecular dyn