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At an appropriate shape memory programming temperature, all synthesized PPS-x-TPUs exhibited excellent shape memory behaviors with a fixed shape rate of 99% and a shape recovery rate of 86% in the first round and 95% in the following rounds. Therefore, these bio-TPUs with shape memory have potential for use in smart fabrics. Copyright © 2020 American Chemical Society.The scaly bulbs of Lilium longiflorum (Liliaceae) are used as a food ingredient and a traditional medicine in East Asia. A preliminary study revealed that treatment