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Hydrochemical investigation of groundwater was carried out on the coastal aquifers of Ogun Waterside, Southwestern Nigeria. Groundwater samples were collected and assayed for physicochemical parameters during wet season (August, 2016) and dry season (March, 2017). The analysed data were further subjected to correlation analysis (CA), principal component analysis (PCA), hydrochemical facies and descriptive statistics. Results revealed that the groundwater is slightly acidic with fresh to saline character. The CA showed very strong assoc