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The integrated SiO2/Fe2O3/Fe anode delivers a stable capacity of 651.7 mA h g-1 at 0.2 A g-1 after 100 cycles. This strategy offers a low-cost route for the rapid fabrication of integrated electrodes, broadening their applications in high cycling-stability LIBs.The two-center three-electron (2c-3e) bonded species are important in chemical and biological science. Reported isolable 2c-3e σ-bonded species are usually constructed in homoatomic radicals. The one-electron oxidation of main-group heteronuclear species Nap(SPh)(P(Mes)2) (1), Nap

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