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Accordingly, mechanisms based on Carman-Kozeny equation and Flory-Huggins lattice theory were proposed to interpret SFR of SMPs with low and high MW, respectively. Simulating these two mechanistic models on PEG samples resulted in the comparable SFR data to the experimental ones, indicating the correctness and feasibility of the proposed mechanisms. The proposed mechanisms provided in-depth understanding of membrane fouling regarding MW, facilitating to develop effective membrane fouling mitigation strategies. CO2 reduction offers an attr