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Taking advantage of the pendant lone pair of the dicoordinated sp2 hybridized N atom, the iminoborane-NHC adduct gives access to NHC-stabilized borenium cation 3 through the reaction with trimethylsilyl triflate (Me3SiOTf) or to the gallium adduct 4 by reacting with GaCl3. Incorporating an iminoborane functional group into a π-conjugated system brings a new bonding situation for broadening the scope of BN-containing polyaromatic systems.Computational screening methods have changed the way new materials and processes are discovered and d

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