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The rotational spectra of 1-butanol (1-BuOH), 1-butanethiol (1-BuSH), 2-methyl-1-propanol (iso-BuOH), and 2-methyl-1-propanethiol (iso-BuSH) were measured by Fourier transform microwave spectroscopy in the frequency region from 3.7 up to 25 GHz. The observed spectral lines were assigned by observation of the deuterium substitution effect and by ab initio or density functional theory calculations at the levels of MP2/6-311++G(d,p) or B3LYP and cam-B3LYP, respectively. For 1-BuOH and 1-BuSH, seven of the 14 conformations, anticipated to e

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