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In the first reported crystal structure involving the potential ligand N,N',N''-tris-(pyridin-2--yl)benzene-1,3,5--tricarboxamide, C24H18N6O3, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder are formed by the hydrogen-bonding inter-actions and the benzene ring cores of the mol-ecules act as the rungs of the ladder. Only two of the three amide groups in the mol-ecule are involved in hydrogen bonding and this influences the degree of out-o

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