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During chlorination of seawater, the presence of bromide and ammonia alters the speciation of the oxidant and lead to the formation of chlorinated and brominated amines. This can affect the effectiveness of the disinfection treatment and the formation of disinfection by-products released to the environment. In this study, a Membrane Introduction Mass Spectrometry (MIMS) analytical method was developed to differentiate brominated trihalamines (i.e. tribromamine NBr3, dibromochloramine NBr2Cl and bromodichloramine NBrCl2) in synthetic and n