https://www.selleckchem.com/pr....oducts/Cyclopamine.h
The catalytic activity in amine-borane dehydrogenation is shown for the first time for Ln(II) species using complexes [(p-tBu-C6H4)2CH2M·L] (M = Yb, Sm, L = (DME)2, TMEDA). The protonation of M(II)-C bonds with HNR1R2BH3 affords amidoborane complexes [M(NR1R2BH3)2L], which under excess HNMe2BH3 transform to [NMe2BH2NMe2BH3]- derivatives, both serving as the dehydrocoupling intermediates.We have assessed the performance and accuracy of different wavefunction-based electronic structure methods, such as DFMP2 and domain-based local pai