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In addition, the assessment of cooperative catalysts to convert carbohydrates into BHMTHF under one-pot cascade, tentative mechanism, as well as prospects and challenges for the chemo-selective hydrogenation of 5-HMF were also highlighted.Metal ions play a significant role in tissue repair, with widely application in clinical treatment. However, the therapeutic effect of metal ions is always limited due to metabolization and narrow repair capability. Here, a bipolar metal flexible electrospun fibrous membrane based on a metal-organic fram