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% of rGO content in polymer blend nanocomposite (BPNC) films. For these BPNC films, the electrochemical stability window (ESW) is ~4.0 V at 25 wt.% of rGO content and ionic transport number (tion) is ~0.98, for 10 wt.% of rGO content at the room temperature. These highly stable blend polymer nanocomposite electrolyte films offer the excellent properties for utilized as a separator for solid-state devices e.g., battery, supercapacitors, electrochromic display devices and other electrochemical energy storage/ conversion devices respective