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A highly efficient fluoride adsorbent Al2 O3 /CeO2 was synthesized in this work, and used it to fluoride removal in the fixed-bed adsorption through changing the different experimental conditions (influent F- concentration, flow velocity and bed heights). The adsorption capacity was 9.72 mg/g. In addition, Adams-Bohart and Thomas models were used to fit and evaluate the column breakthrough curve of fluoride removal process by Al2 O3 /CeO2 , and the correlation coefficients (R2 ) of Thomas model were close to 1 under all experimental cond

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