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Nowadays, the PFCs toxic mechanisms discussed are limited to a single strain, Escherichia coli; thus, the complexity of the soil environment demands further in-depth researches. This review warrants studies focus on more potential quantitative toxicity indicators, more explicit elaboration on toxicity influencing factors, and environmentally relevant concentrations to obtain a more integrated picture of PFCs toxicity on terrestrial biota.This paper presents an eco-efficiency analysis of five scenarios for treating a petrochemical unit ef