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Brown carbon (BrC), a significant wavelength-dependent atmospheric absorber of solar radiation, plays a key role in photochemistry and long-lasting haze episodes. Herein, two types of BrC extracted from one-year PM2.5 samples (June 2017-May 2018 in Nanjing), i.e. methanol-extracted organic carbon (MSOC) and ultrapure water-extracted organic carbon (WSOC), were obtained to investigate distinct optical properties of atmospheric BrC. The extraction efficiency of BrC was as high as 91% in methanol solution, and the corresponding light absorpt