https://www.selleckchem.com/pr....oducts/tradipitant.h
The intersection between Cu-catalyzed atom transfer radical polymerization (ATRP) and organometallic mediated radical polymerization (OMRP) has been recently shown to be a result of competition between the CuI and CuII complexes of polyamine ligands for the same organic free radical. The tetradentate ligands N,N'-bis-2'-pyridylmethyl-ethane-1,2-diamine (L1) and N,N'-dimethyl-N,N'-bis-2'-pyridylmethyl-ethane-1,2-diamine (L2) form stable Cu complexes which, depending on their oxidation state, can either liberate or complex organic rad
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