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The [Fe2S2]2- case shows the general usefulness of the method.Intercalation of carbon nanosheets into two-dimensional (2D) inorganic products could boost their properties when it comes to mechanics and electrochemistry, but sandwiching these two forms of materials in an alternating series is a good challenge in synthesis. Herein, we report a novel strategy to construct TiO2 nanosheets into 2D pillar-layer architectures by utilizing benzidine molecular system as pillars. Then, 2D carbon/T