https://www.selleckchem.com/pr....oducts/Rapamycin.htm
© 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.Copper-oxo clusters exchanged in zeolite mordenite are active in the stoichiometric conversion of methane to methanol at low temperatures. Here, we show unprecedented methanol yield per Cu of 0.6, with a 90-95 % selectivity, on a MOR solely containing [Cu3(μ-O)3]2+ active sites. DFT calculations, spectroscopic characterization and kinetic analysis show that increasing the chemical potential of methane enables the utilization of two µ-oxo bridge oxygen out of the three available in
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