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Increased analytical efforts must be implemented to improve product quality.There have been two known categories of porphyrins a meso-substituted porphyrin like meso-tetramesitylporphyrin (TMP) and a pyrrole-β-substituted porphyrin like native porphyrins and 2,7,12,17-tetramethyl-3,8,13,18-tetramesitylporphyrin (TMTMP). To reveal the chemical and biological function of native hemes, we compare the reactivity of the oxoiron(IV) porphyrin π-cation radical complex (Compound I) of TMP (TMP-I) with that of TMTMP (TMTMP-I) for epoxidation, h
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