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© 2020 Australian and New Zealand Society for Immunology Inc.The results of extended comparative investigation of the Ni(II) Schiff base complexes (containing various auxiliary chiral moieties) commonly used as a methodological platform for the asymmetric synthesis of tailor-made α-amino acids are provided. The following issues are addressed 1) redox activity (determining the possibility for electrochemically induced reactions); 2) quantitative estimation of the reactivity of the deprotonated complexes towards electrophiles; 3) quantum-c
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