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The numerical simulations verify the analytical results and identify the requirements of length of sensing phase and transmit power for the maximum residual energy in both reliable and secure communication scenarios. Additionally, it is shown that the residual energy in secure communication is lower than that in reliable communication.Over the past years, a great effort has been devoted to the development of new sorbents that can be used to pack or to coat extractive capillaries for in-tube solid-phase microextraction (IT-SPME). Many of