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Despite much progress toward assisting directional transport by multilayer permeable membranes with opposite wettability, it remains tough to attain a highly multifunctional flexible membrane layer for highly efficient unidirectional liquid transportation in numerous situations. Herein, a superhydrophilic-hydrophilic self-supported monolayered permeable poly(ether sulfone) (PES) membrane layer with special nano- and micropores at opposite areas is demonstrated, which can