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Accordingly, a promising architecture of passive nanoparticle-carrying core and thermoresponsive shell was realized successfully.The complex effects of nanoparticles on a thermosetting material based on an anhydride cured DGEBA/boehmite nanocomposite with different particle concentrations are considered. A combination of X-ray scattering, calorimetry, including fast scanning calorimetry and temperature modulated calorimetry, and dielectric spectroscopy was employed to study the structure, the vitrification kinetics and the molecular dyna