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In this work, we report the synthesis, photophysics, and electrochemistry of a new array of trinuclear complexes, [(bpy)2Os(d-HIm-t)M(t-HIm-d)Os(bpy)2]6+ (M = FeII, RuII, and OsII), based on a previously reported bipyridine-terpyridine type bridge (d-HIm-t). Photophysical behavior of in situ generated trinuclear OsZnOs complex [(bpy)2Os(d-HIm-t)Zn(t-HIm-d)Os(bpy)2]6+ was also investigated to understand the complicated photophysics of trinuclear array. Complexes display very rich redox properties demonstrating multiple metal-based oxidation and