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t the surface as the pristine implant.The reactivity of the P4 butterfly complex [Cp'''Fe(CO)2 2 (μ,η11 -P4 )] (1, Cp'''=η5 -C5 H2 tBu3 ) towards divalent Co, Ni and Zn salts is investigated. The reaction with the bromide salts leads to [Cp'''Fe(CO)2 2 (μ3 ,η211 -P4 )MBr2 ] (M=Co (2Co), Ni (2Ni), Zn (2Zn)) in which the P4 butterfly scaffold is preserved. The use of the weakly ligated Co complex [CNCCH3 )6 ][SbF6 ]2 , results in the formation of [(Cp'''Fe(CO)2 )2 (μ3 ,η411 -P4 )2 Co][SbF6 ]3 (3), which represents the second example of a
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