https://www.selleckchem.com/pr....oducts/gsk2126458.ht
Direct CH4 photoconversion into liquid oxygenates under mild conditions still represents a huge challenge. Herein, two-dimensional oxide semiconductors are designed to generate abundant active O- species for activating C-H bond of methane. Taking the synthetic ZnO nanosheets as an example, in situ electron paramagnetic resonance spectra verified their lattice oxygen atoms could capture photoexcited holes and generate active O- species, which could efficiently abstract H from CH4 to generate ·CH3 radicals. Gibbs free energy calculatio
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