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All rights reserved.Improving electrical conductivity of sulfur, controlling shuttle/dissolution of polysulfide and enhancing reaction kinetics in Li-S battery packs are crucial for practical application. Herein, the very first time, we make use of low cost oleic acid as solitary carbon origin, and add commercial SiO 2 as template to make porous construction while introducing Fe(NO 3 ) 3 and Ni(NO 3 ) 2 as catalysts to increase their education of graphitization. In addition, du