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The observed rotational constants of Pyr-Ne are in line with a nearly symmetric prolate top because of the Ne atom located over the airplane of pyrrole. The trimer presents C2v symmetry utilizing the Ne atoms located one for each region of the ring plane. The experimental 14N nuclear quadrupole coupling constants have been determined for all the isotopologues of Pyr-Ne and Pyr-Ne2 buildings. Similar values to those of isolated pyrrole were found, which implies that the elect

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