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Stabilization of initial adducts along with HF elimination are important reaction pathways under high pressure and low temperatures. Important HF eliminations and H atom transfers primarily involve H atoms from the hydroxyl group, as the C-H bonds on or adjacent to carbons with F atoms are stronger and show high barriers to H atom transfer.It is still a challenge to achieve efficiently controlled preparation of functional oxygen reduction reaction (ORR) carbon electrocatalysts with multi-preferred structures (hierarchically porous networks