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The effect of additives of polydimethylsiloxanes (PDMS) with various molecular weights on the morphology and rheological behavior of polyacrylonitrile (PAN) solutions in dimethyl sulfoxide has been analyzed. It was shown that only partial compatibility of the PDMS with the lowest molecular weight member of the homologous series studied-hexamethyldisiloxane-with PAN solution takes place. All other PDMS samples form emulsions with PAN solutions. The coalescence rate of PDMS drops depends on the viscosity ratio of the disperse phase and the
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