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Copyright © 2020 American Chemical Society.Nanomaterials that comprise titanium dioxide (TiO2) nanoparticles have received much attention owing to their wide applications; presently, the green synthesis of TiO2 nanoparticles is a developing research area. In this study, the TiO2 nanoparticles were synthesized through a DC-pulsed discharge plasma over an aqueous solution surface under a high-pressure argon environment. The titanium-rod electrode was utilized as the material source for the TiO2 nanoparticle generation. Experiments were pe