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Facile access to such analogues serves to expand the repertoire of available enzymatically cleavable linkers for ADC generation. This methodology empowers a robust and facile library generation and future exploration into linker analogues containing unnatural amino acids as a selectivity tuning tool.The self-assembly of plasmonic nanoparticles into highly ordered superlattices could pave the way toward novel nanomaterials for surface-enhanced Raman scattering (SERS). Here, we propose the formation of large-area superlattices of elongated r