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It could also distinguish between polymer series (before and after degradation) to identify their separate spatial distributions. A machine-learning method for peak extraction from high-resolution MALDI-TOFMS was developed. Single-component peaks of the mass spectrum were distinguished from noise peaks by their peak shapes. Combining with KMD analysis facilitated the identification of minor polymer series in complex mass spectra. A machine-learning method for peak extraction from high-resolution MALDI-TOFMS was developed. Single-componen