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assist rod-units towards a wider, self-assembled structure. The effective wetting area, a parameter somewhat different from the apparent contact area at solid-liquid interfaces, plays a significant role in surface wettability. However, determination of the effective wetting area for hydrophobic surfaces remains an open question. In the present study, we developed an electrochemical impedance method to evaluate the effective wetting area at a hydrophobic solid-liquid interface. Patterned Si surfaces were prepared using the anisotropic we
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