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The temperature-dependent rate coefficient in the studied temperature range was obtained to be kphenyl + EtOAcTheory - (200 - 400 K) = (7.68 ± 0.12) × 10-17 exp[(1731.6 ± 216./T] cm3 molecule-1 s-1, and the rate coefficient at 298 K was obtained as kphenyl + EtOAcTheory - 298 K = 2.45 × 10-14 cm3 molecule-1 s-1. Both the experimentally measured and computed rate coefficients show good agreement at 298 K. A negative temperature dependency was observed for both the experimentally measured and computed rate coefficients. A