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The static and powerful first- and second-order hyperpolarizabilities were determined making use of the time-dependent thickness useful concept during the B3LYP/6-31+G* degree. The calculated fixed values of β and γ of RhAP by the X-ray diffraction (XRD) structure were 31.9 × 10-30 and 199.0 × 10-36 esu, correspondingly. These values were about 62 times larger than the corresponding values in urea, a currently well-known nonlinear optical product. The second-order hy
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