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To investigate the quasi-shear wave behavior and the underlying microscopic mechanism of an anisotropic solid under dynamic deformation beyond its Hugoniot elastic limit, LiF single crystals are shock-compressed along the [310] low-symmetry crystallographic orientation via normal plate-impact method. Interfacial velocity profiles are measured with a Doppler pin system. Peak normal stresses in samples vary between 1.91 GPa and 3.23 GPa. Under the lowest stress in this study, the resultant wave profile shows typical elastoplastic two-wave
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