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The results indicated that the generation of 2.8-DCDD had been observed in matrices with Cl-. The Fe/Nb2O5-immobilized catalysts had been efficient in the degradation of triclosan and 2.8-dichlorodibenzene-p-dioxin. But, 2.8-DCDD formation was not seen in the ultra-pure water matrix, which indicated impact of ions. The photocatalysis ended up being more efficient as compared to photolysis when comparing both matrices and radiation. Despite having a radiation oscillation, the solar power process r