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Overall, this work provides fundamental insights into the organocatalytic ROP of these specific six-membered asymmetric cyclic glucose carbonates. More importantly, these findings serve as a foundation for future design strategies that incorporate adjacent functionalities within monomers to act as directing groups and impart molecular interactions that define regiochemical ring-opening.Polyoxometalate molybdenum blue (M complexes typically exist as discrete multianionic clusters and are composed of repeating Mo building units. MB whee
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